Polyester fiber blends and methods of manufacturing same

ABSTRACT

This application is directed to polymer blends of polyethylene naphthalate, polytrimethylene terephthalate, and polyethylene naphthalate, for use in fibers, such as carpet fibers, and other applications. This application is also directed to methods of producing such polymer blends and fibers.

RELATED APPLICATIONS

This application claims the benefit of U.S. Provisional Application No.62/313,356, filed Mar. 25, 2016, which is hereby incorporated byreference in its entirety.

FIELD

The invention relates to polymeric fiber blends, and particularlypolyester fiber blends comprising polyethylene terephthalate (PET),polytrimethylene terephthalate (PTT), and polyethylene naphthalate(PEN), useful in carpet yarns and carpets. The invention further relatesto methods of improving physical characteristics of PET carpet fibersthrough the addition of PTT and PEN in polymeric blends, and methods ofpreparing manufacturing bulked continuous carpet filaments comprising aPET/PTT/PEN blend.

BACKGROUND

Carpets, rugs, mats, and like floor coverings used in home andindustrial applications are typically made from natural fibers (such ascotton and wool) or synthetic fibers (such as nylon, polyester,polyolefins, acrylics, rayon, and cellulose acetate). Synthetic fiberstend to be more favored in carpet manufacture, as they are generallymore commercially acceptable and can be used for a wider variety ofapplications.

Polyethylene terephthalate (PET), a thermoplastic fiber polymer resin inthe polyester family, is a commonly used synthetic fiber for carpetapplications. One of the drawbacks of PET carpets is that they havelower dyeability (i.e. are less easily dyed) than other types ofcarpets, such as nylon.

Polytrimethylene terephthalate (PTT) is another polyester which may beused in carpeting. One way of improving the dyeability of PET is byblending it with PTT. However, adding PTT to PET in amounts high enoughto create deep dyeing PET, reduces the strength of the fiber, meaningthat the PET/PTT blend fiber will not be suitable for furtherprocessing.

Accordingly, a need exists for a PET/PTT blended carpet with improvedstrength qualities, and deep dyeability.

SUMMARY

The present invention provides fibers comprising polymeric blends ofpolyethylene terephthalate (PET), polytrimethylene terephthalate (PTT),and polyethylene naphthalate (PEN) providing improved strength anddyeability properties compared to either a PET/PTT or PET/PEN polymericblend.

In an embodiment, the blend comprises about 1% to about 15%polytrimethylene terephthalate and about 1% to about 15% polyethylenenaphthalate, wherein the balance is polyethylene terephthalate.

The invention also provides a carpet or a yarn comprising such fibers.

The invention also provides a method of using a multi-screw extruder tomanufacture a bulked continuous carpet filament using a polymeric blendof PET, PTT, and PEN.

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING(S)

Reference will now be made to the accompanying drawing, which is notnecessarily drawn to scale, and wherein:

FIG. 1 is a cross-section diagram of a tufted carpet in accordance withan embodiment of the present invention.

FIG. 2 is a perspective view of an MRS extruder that is suitable for usein a process for manufacturing bulked continuous filament.

FIG. 3 is a cross-sectional view of an exemplary MRS section of the MRSextruder of FIG. 2.

FIG. 4 depicts a process flow depicting the flow of polymer through anMRS extruder and filtration system according to a particular embodiment.

FIG. 5 depicts the dyed sleeves used to test dyeability in Example 1.The numbers represent the sleeve numbers, and the heads of the sleeves(i.e. the portion containing Fiber 1) are at the bottom of the Figure.

DETAILED DESCRIPTION

The present invention now will be described more fully hereinafter withreference to the accompanying drawings, in which some, but not allembodiments of the inventions are shown. Indeed, these inventions may beembodied in many different forms and should not be construed as limitedto the embodiments set forth herein; rather, these embodiments areprovided so that this disclosure will satisfy applicable legalrequirements. Like numbers refer to like elements throughout. In thefollowing description, various components may be identified as havingspecific values or parameters, however, these items are provided asexemplary embodiments. Indeed, the exemplary embodiments do not limitthe various aspects and concepts of the present invention as manycomparable parameters, sizes, ranges, and/or values may be implemented.The terms “first,” “second,” and the like, “primary,” “exemplary,”“secondary,” and the like, do not denote any order, quantity, orimportance, but rather are used to distinguish one element from another.Further, the terms “a,” “an,” and “the” do not denote a limitation ofquantity, but rather denote the presence of “at least one” of thereferenced item.

Each embodiment disclosed herein is contemplated as being applicable toeach of the other disclosed embodiments. All combinations andsub-combinations of the various elements described herein are within thescope of the invention.

It is understood that where a parameter range is provided, all integerswithin that range, and tenths and hundredths thereof, are also providedby the invention. For example, “5-10%” includes 5%, 6%, 7%, 8%, 9%, and10%; 5.0%, 5.1%, 5.2% . . . 9.8%, 9.9%, and 10.0%; and 5.00%, 5.01%,5.02% . . . 9.98%, 9.99%, and 10.00%.

As used herein, “about” in the context of a numerical value or rangemeans ±10% of the numerical value or range recited or claimed.

As used herein, “recycled” refers to any material that is post-consumeror post-industrial material.

As used herein, “post-consumer” means a component part, intermediate, orfinal product that contains in whole, or in significant part, a wastematerial produced by the end consumer of a material stream.

As used herein, “post-industrial” means a component part, intermediate,or final product that contains in whole, or in significant part, a wastematerial produced prior to the end consumer of a material stream andwhich may be reintroduced as manufacturing scrap back into the same ordifferent manufacturing process.

As used herein, “deep dyeability” refers to a dye strength increase ofthree times.

Embodiments of the invention are directed to a polymeric blendcomprising PET, PTT and PEN, and in particular to fibers and yarnscomprising the polymeric blend. Typically, the amount of PTT in thepolymeric blend is from about 1 to 15 weight percent, and in particularfrom about 5 to 15 weight percent, and more particularly from about 5 to12 weight percent, and more particularly from about 8 to 12 weightpercent, and more particularly from about 8 to 10 weight percent, basedon the total weight of the blend. Similarly, the amount of PEN in thepolymeric blend is from about 1 to 15 weight percent, and in particularfrom about 5 to 15 weight percent, and more particularly from about 5 to12 weight percent, and more particularly from about 8 to 12 weightpercent, and more particularly from about 8 to 10 weight percent, basedon the total weight of the blend. Typically, PET comprises the remainingbalance of the polymeric blend. For example, the amount of PET in theblend may range from about 68 to 98 weight percent, with an amount ofPET being from about 75 to 85 weight percent, and from 78 to 84 weightpercent, based on the total weight of the blend being somewhat morepreferred.

In an embodiment, the fiber contains about 8% by weight PTT and about10% by weight PEN.

In an embodiment, the fiber is as-spun. In another embodiment, the fiberis heat-set.

In embodiments, the fiber exhibits increased dyeability compared to asimilar fiber where a portion, or all, of the polytrimethyleneterephthalate is replaced by polyethylene terephthalate. In anembodiment, the fiber the fiber exhibits increased dyeability comparedto a similar fiber where a portion, or all, of the polytrimethyleneterephthalate is replaced by polyethylene terephthalate. In embodiments,the increase in dyeability is at least about 1% to at least about 300%.

In an embodiment, the increase in dyeability caused by the addition ofpolyethylene naphthalate and polytrimethylene terephthalate topolyethylene terephthalate is greater than the sum of the increase indyeability caused by adding polyethylene naphthalate to polyethyleneterephthalate and the increase in dyeability caused by addingpolytrimethylene terephthalate to polyethylene terephthalate.

In an embodiment, the fiber exhibits an improvement in a physicalcharacteristic selected from the group consisting of total recovery,elongation, crimp, tenacity, and shrinkage, compared to a similar fiberwhere a portion of the polyethylene naphthalate is replaced by acombination of polyethylene terephthalate. In a further embodiment, theimprovement is at least 1% to at least 25%.

In an embodiment, at least one, preferably at least two, and morepreferably all three of the polyethylene terephthalate polymer, thepolytrimethylene terephthalate polymer, and the polyethylene naphthalatepolymer are recycled.

The polymeric blends of the present invention may further comprise othercomponents, such as, without limitation, finishing agents, delusterants,viscosity boosters, optical brighteners, matting agents (e.g., titaniumoxide), thermal stabilizing agents (e.g., phosphorous compounds),anti-oxidative agents (e.g., hindered phenol), anti-static agents,pigments, ultra-violet blocking agents, and combinations thereof. See,for example, U.S. Pat. No. 6,921,803, which is incorporated herein byreference in its entirety.

A wide variety of different PET may be used as the PET component in thepolymeric blend. For example, the PET polymer can comprise LASER+® PET(available from DAK Americas), NAN YA® PET (Nan Ya Plastics Corporation,America), other PET polymers, or combinations thereof. PET can beproduced, for example, by a transesterification reaction of dimethylterephthalate and ethylene glycol, or by esterification of terephthalicacid and ethylene glycol. PET may be provided from both virgin andrecycled resins. In a preferred embodiment, the PET comprises recycledPET that is recovered from soda and water bottles. The PET may be inflake or pellet form in any of the embodiments described herein.

In an embodiment, the intrinsic viscosity (IV) of the PET used in theembodiments of the invention is at least about 0.60 dL/g. In a furtherembodiment, the IV is in a range from about 0.60 dL/g to about 1.00dL/g. In a further embodiment, the IV is in a range from about 0.75 dL/gto about 1.00 dL/g.

The PTT component can comprise PTT belonging to one or more differenttypes of PTT polymer. For example, the PTT polymer can comprise SORONA®PTT (available from E.I. Du Pont de Nemours), other PTT polymers, orcombinations thereof. PTT is generally produced by the polycondensationreaction of purified terephthalic acid (PTA) and 1,3-propanediol (PDO).Some PTT is produced solely by chemical reaction of petroleum basedingredients, while SORONA® PTT is produced using PDO obtained bybacterial metabolism.

In an embodiment, the IV of the PTT used in the embodiments of theinvention is in a range from about 0.8 dL/g to about 1.04 dL/g. In afurther embodiment, the IV of the PTT is in a range from about 0.86 dL/gto about 0.98 dL/g. In a further embodiment, the IV of the PTT is about0.92 dL/g.

The PEN component may comprise PEN belonging to one or more types of PENpolymer. For example, the PEN component may comprise PEN produced withprecursors provided by BP-Amoco®, other PEN, or combinations thereof.PEN may be produced, for example, by the polycondensation reaction ofnaphthalene-2,6-dicarboxylic acid (2,6-NDA) or a functional derivative,with ethylene glycol. PEN may be provided from both virgin and recycledresins. In a preferred embodiment, the PEN component comprises arecycled resin. The PEN may be in flake, pellet, or condux form.

In an embodiment, the IV of the PEN used in the embodiments of theinvention is in a range from about 0.4 dL/g to about 0.9 dL/g. In afurther embodiment, the IV of the PEN is in a range from about 0.53 dL/gto about 0.78 dL/g.

The fibers may be manufactured as bulked continuous filament (BCF).

The invention also provides a method of manufacturing bulked continuouscarpet filament, said method comprising:

-   -   (A) providing a multi-screw extruder that comprises:        -   (i) a first satellite screw extruder, said first satellite            screw extruder comprising a first satellite screw that is            mounted to rotate about a central axis of said first            satellite screw;        -   (ii) a second satellite screw extruder, said second            satellite screw extruder comprising a second satellite screw            that is mounted to rotate about a central axis of said            second satellite screw; and        -   (iii) a pressure regulation system that is adapted to            maintain a pressure within said first and second satellite            screw extruders between about 0 millibars and about 1.8            millibars;    -   (B) using said pressure regulation system to reduce a pressure        within said first and second satellite screw extruders to        between about 0 millibars and about 1.8 millibars;    -   (C) while maintaining said pressure within said first and second        satellite screw extruders between about 0 millibars and about        1.8 millibars, passing a melt comprising a polymer through said        multi-screw extruder so that: (1) a first portion of said melt        passes through said first satellite screw extruder, and (2) a        second portion of said melt passes through said second satellite        screw extruder; and    -   (D) after said step of passing said melt of polymer through said        multi-screw extruder, forming said polymer into a bulked        continuous carpet filament;        wherein said bulked continuous carpet filament comprises a        polymer blend comprising a polyethylene terephthalate polymer, a        polytrimethylene terephthalate polymer, and a polyethylene        naphthalate polymer.

In a further embodiment, said polymer is a polyethylene terephthalatepolymer, and further comprising after step (C) and before step (D),cooling said melt of polymer so as to form pellets, and mixing saidpellets with polytrimethylene terephthalate polymer pellets, andpolyethylene naphthalate polymer pellets.

In a further embodiment, said extruder is a first extruder; and saidmethod further comprises:

-   -   i) passing a plurality of flakes of PET through a second        extruder; and    -   ii) while passing said plurality of flakes through said second        extruder, using said second extruder to heat said plurality of        flakes to a temperature that is sufficient to at least        substantially melt said plurality of polyester flakes to form        said polymer melt.

In a further embodiment, wherein said PET flakes are recycled PETflakes, and wherein said method further comprises, before said step ofpassing said plurality of flakes through said second extruder:

-   -   washing said plurality of PET flakes;    -   scanning said washed plurality of PET flakes to identify any of        said plurality of flakes that comprise material other than PET;        and    -   removing at least one of said identified flakes that comprise        material other than PET.

In another embodiment, the melt in step (C) is a melt comprisingpolyethylene terephthalate, polyethylene naphthalate, andpolytrimethylene terephthalate.

In a further embodiment, the PTT is not dried prior to step (C).

A further advantage of the invention is that the PET, PEN, and PTT canbe recovered from previously prepared materials (e.g., recycled fromsoda bottles or other materials). Of course, the invention is notlimited to the use of recycled PET, PEN, and PTT. Rather, virgin PET,PEN, and PTT (or a mixture of virgin and recycled PET, PEN, and PTT)could be used to spin the novel fiber. Moreover, the PET, PEN, and PTTused in the fibers of the invention can be substantially pure PET, PEN,and PTT or can each be copolymers comprising one or more comonomers.Unless otherwise noted, each of the PET, PEN, and PTT used in any of theembodiments of the invention may be virgin, recycled, or a blendthereof. In a preferred embodiment, the PTT is virgin polymer and thePEN and PET are recovered from previously prepared materials.

The fibers may be formed from the polymer blend by any method known inthe art to produce fibers from a single polyester or from a blend. Thepolymeric blend can be extruded to have any shape or dimension suitableto polymeric carpet fibers. Moreover, the carpet fibers can undergo anypost-spinning processes generally recognized as useful in thepreparation of polymeric carpet fibers. By “fibers”, reference is madeto items, recognized in the art as fibers, such as continuous filaments,monofilaments, staple fibers, and the like. The fibers can be round orhave other shapes, such as octalobal, delta, sunburst (also known assol), scalloped oval, trilobal, tetra-channel (also known asquatra-channel), scalloped ribbon, ribbon, starburst, and the like. Thefibers may also be solid, hollow, or multi-hollow. The fibers can beused to make yarns, and the fibers or yarns can be used to prepare anumber of materials, particularly carpets, rugs, mats, and the like.

In one embodiment, the invention provides yarns prepared using thefibers described herein. The yarns may be prepared according to anymethod for preparing yarns recognized in the art as being usefultherefore. For example, the yarn of the invention could be partiallyoriented yarn, spun drawn yarn, textured yarn, friction false-twistedyarn, and bulk continuous filament (“BCF”) yarn. Partially oriented andfriction false-twisted yarns of PTT are described in U.S. Pat. No.6,287,688 and U.S. Pat. No. 6,333,106; BCF yarns are described in U.S.Pat. No. 5,645,782, U.S. Pat. No. 6,109,015, and U.S. Pat. No.6,113,825, all of the above being incorporated herein by reference intheir entireties. Preferred steps in preparing BCF yarn includesspinning (e.g., extruding, cooling, and coating filaments), single stageor multi-stage drawing (such as with heated rolls, heated pin or hotfluid assist) at a defined temperature and draw ratio, annealing,bulking, entangling, optionally relaxing, and winding the filaments on apackage for subsequent use.

The invention also provides for a carpet comprising a fiber or a yarn asdescribed hereinabove. One embodiment of carpet, a tufted carpet,includes fiber tufts, backing, filler material, and adhesive material.In some arrangements, the backing can include two components: theprimary backing and the secondary backing.

One such construction of carpeting is illustrated schematically in FIG.1, and is generally designated by reference numeral 1. The carpet 1includes face yarn 2, which is tufted into a mesh, woven, or spunbondedfabric known as a primary backing 5. The primary backing 5 has pileyarns 2 tufted therethrough extending outwardly from one face, a primarybackcoating or precoat 3 on the opposite face, and at least onesecondary backcoating or main coat (frequently called a skip coat) 4.Other layers may also be associated with the carpet 1.

The primary backcoating or precoat 3 generally comprises carboxylatedlatex (e.g., a styrene-butadiene-based latex), PVC (polyvinylchloride),EVA (ethylene-vinyl acetate), or other polymer-based material, and thesecondary backcoating 4 may also include polymers. One or both of theprimary backcoatings 3 and secondary backcoating(s) 4 can include afiller material. The most common filler is a mineral filler, such ascalcium carbonate, although other fillers, such as alumina trihydrate,bauxite, magnesium hydroxide, or the like, may be utilized. In certainsituations, calcium carbonate can be used with other common materialssuch as metal salts. The carpet 1 may be produced with the filler in oneor both of the primary backcoating 3 and secondary backcoating(s) 4comprising waste carpeting as all or part of the filler.

The carpet 1 may also include any number of other layers, depending uponits intended use. For example, the carpet 1 may have a secondarybacking, such as a woven or non-woven (e.g., spunbonded, melt blown,hydroentangled, or needle punched) fabric adapted to contact the flooror padding.

In making the carpet 1, generally, the fiber tufts are tufted through awoven or non-woven fabric, which is the primary backing 5. The part ofthe tufts on the exposed surface of the carpet comprises the face fiberor face yarn 2. A primary backcoating 3 is applied to the back of thetufted structure to lock in the tufts. Next, a woven or non-wovensecondary backing 4 is attached to the back of the primary backing 5 togive the carpet added dimensional stability.

The primary backing is a supportive scrim through which the tufts aretufted, and is frequently is polyolefin, such as polyethylene orpolypropylene; however, other materials such as polyester (including,for example, PET) can be used. For example, PET may be used. Thesecondary backing is a fabric that is adhered behind the primarybacking, sandwiching therein the back of the tufts with the adhesivematerial. The secondary backing is frequently made of polypropylene;however other backing types, such as jute, PVC (polyvinyl chloride),polyurethane, and PET, can be used. The secondary backing may be anon-woven fabric, including, but not limited to, spun-bond, wet-laid,melt-blown, and air-entangled. A polyurethane foam or other cushioningmaterial may be laminated or otherwise attached to the back side of thecarpet.

A filler material, such as calcium carbonate, and an adhesive materialare generally applied to the backside of the tufted carpet backing as aslurry in various concentrations. There is almost always more fillerthan adhesive material. For example, a representative filler-to-adhesiveratio can comprise about 80 percent by weight (“wt %” or “%”) calciumcarbonate to about 20 wt % adhesive. While calcium carbonate is one ofthe most commonly employed filler materials, it should be recognized bythose skilled in the art to which this disclosure pertains that carpetscontaining other filler materials can be used in the recycling processesdescribed herein.

The adhesive material functions to bind the tufts with the backing. Theadhesive material can include a latex, such as acarboxylic-styrene-butadiene rubber, styrene-butadiene rubber (SBR),natural rubber latex, vinyl acetate ethylene copolymers (VAE or EVA),other natural or synthetic rubbers, urethanes or polymers such as PET.While latex is one of the most commonly employed adhesive materials forholding tufts to the carpet backing, it should be recognized by thoseskilled in the art to which this disclosure pertains that carpetscontaining other adhesives can be used in the processes describedherein.

In an embodiment, the fiber is processed through a continuous dyeingoperation or through a beck dyeing operation. The fiber may optionallybe treated with a soil release agent and/or a soil repellency agent onthe dyeline.

DISCUSSION AND EXAMPLES

As discussed hereinabove, the addition of PTT to PET fibers results in afiber with greater dyeability. Accordingly, it would be desirable to adda large amount of PTT to the PET fibers in order to maximize dyeability.The downside is that adding PTT to the PET reduces the tensile strengthof the blend, compared to the pure PET fiber. Adding PEN to the blendimproves fiber tensile strength without sacrificing the improvements indyeability gained from the addition of PTT. In some embodiments, addingPEN improves both the dyeability and the tensile strength.

As mentioned hereinabove, one method for producing fibers of the currentinvention is via a Multiple Rotating Screw (MRS) extruder, as describedin U.S. Pat. No. 8,597,553, which is hereby incorporated by reference inits entirety. This process produces bulked continuous filament (BCF).

A BCF (bulked continuous filament) manufacturing process, according tothe particular embodiment, may generally be broken down into four steps:(1) preparing flakes of PET polymer from post-consumer bottles for usein the process; (2) passing the flakes through an extruder that meltsthe flakes and purifies the resulting PET polymer; (3) combining thepurified PET polymer with PTT and PEN polymer; and (4) feeding thecombined polymer into a spinning machine that turns the polymer intofilament for use in manufacturing carpets. These steps are described ingreater detail below.

Step 1: Preparing Flakes of PET Polymer from Post-Consumer Bottles

In a particular embodiment, the step of preparing flakes of PET polymerfrom post-consumer bottles comprises: (A) sorting post-consumer PETbottles and grinding the bottles into flakes; (B) washing the flakes;and (C) identifying and removing any impurities or impure flakes.

A. Sorting Post-Consumer PET Bottles and Grinding the Bottles intoFlakes

In particular embodiments, bales of clear and mixed colored recycledpost-consumer (e.g., “curbside”) PET bottles (or other containers)obtained from various recycling facilities make-up the post-consumer PETcontainers for use in the process. In other embodiments, the source ofthe post-consumer PET containers may be returned ‘deposit’ bottles(e.g., PET bottles whose price includes a deposit that is returned to acustomer when the customer returns the bottle after consuming thebottle's contents). The curbside or returned “post-consumer” or“recycled” containers may contain a small level of non-PET contaminates.The contaminants in the containers may include, for example, non-PETpolymeric contaminants (e.g., PVC, PLA, PP, PE, PS, PA, etc.), metal(e.g., ferrous and non-ferrous metal), paper, cardboard, sand, glass orother unwanted materials that may find their way into the collection ofrecycled PET. The non-PET contaminants may be removed from the desiredPET components, for example, through one or more of the variousprocesses described below.

In particular embodiments, smaller components and debris (e.g.,components and debris greater than 2 inches in size) are removed fromthe whole bottles via a rotating trammel. Various metal removal magnetsand eddy current systems may be incorporated into the process to removeany metal contaminants. Near Infra-Red optical sorting equipment such asthe NRT Multi Sort IR machine from Bulk Handling Systems Company ofEugene, Oreg., or the Spyder IR machine from National RecoveryTechnologies of Nashville, Tenn., may be utilized to remove any loosepolymeric contaminants that may be mixed in with the PET flakes (e.g.,PVC, PLA, PP, PE, PS, and PA). Additionally, automated X-ray sortingequipment such as a VINYLCYCLE machine from National RecoveryTechnologies of Nashville, Tenn. may be utilized to remove remaining PVCcontaminants.

In particular embodiments, a binary segregation of the clear materialsfrom the colored materials is achieved using automated color sortingequipment equipped with a camera detection system (e.g., an Multisort ESmachine from National Recovery Technologies of Nashville, Tenn.). Invarious embodiments, manual sorters are stationed at various points onthe line to remove contaminants not removed by the sorter and anycolored bottles. In particular embodiments, the sorted material is takenthrough a granulation step (e.g., using a 50B Granulator machine fromCumberland Engineering Corporation of New Berlin, Wis.) to size reduce(e.g., grind) the bottles down to a size of less than one half of aninch. In various embodiments, the bottle labels are removed from theresultant “dirty flake” (e.g., the PET flakes formed during thegranulation step) via an air separation system prior to entering thewash process.

B. Washing the Flakes

In particular embodiments, the “dirty flake” is then mixed into a seriesof wash tanks. As part of the wash process, in various embodiments, anaqueous density separation is utilized to separate the olefin bottlecaps (which may, for example, be present in the “dirty flake” asremnants from recycled PET bottles) from the higher specific gravity PETflakes. In particular embodiments, the flakes are washed in a heatedcaustic bath to about 190 degrees Fahrenheit. In particular embodiments,the caustic bath is maintained at a concentration of between about 0.6%and about 1.2% sodium hydroxide. In various embodiments, soapsurfactants as well as defoaming agents are added to the caustic bath,for example, to further increase the separation and cleaning of theflakes. A double rinse system then washes the caustic from the flakes.

In various embodiments, the flake is centrifugally dewatered and thendried with hot air to at least substantially remove any surfacemoisture. The resultant “clean flake” is then processed through anelectrostatic separation system (e.g., an electrostatic separator fromCarpco, Inc. of Jacksonville, Fla.) and a flake metal detection system(e.g., an MSS Metal Sorting System) to further remove any metalcontaminants that remain in the flake. In particular embodiments, an airseparation step removes any remaining label from the clean flake. Invarious embodiments, the flake is then taken through a flake colorsorting step (e.g., using an OPTYX sorting machine from Key Technologyof Walla Walla, Wash.) to remove any remaining color contaminantsremaining in the flake. In various embodiments, an electro-optical flakesorter based at least in part on Raman technology (e.g., a Powersort 200from Unisensor Sensorsysteme GmbH of Karlsruhe, Germany) performs thefinal polymer separation to remove any non-PET polymers remaining in theflake. This step may also further remove any remaining metalcontaminants and color contaminants.

In various embodiments, the combination of these steps deliverssubstantially clean (e.g., clean) PET bottle flake comprising less thanabout 50 parts per million PVC (e.g., 25 ppm PVC) and less than about 15parts per million metals for use in the downstream extrusion processdescribed below.

C. Identifying and Removing Impurities and Impure Flakes

In particular embodiments, after the flakes are washed, they are feddown a conveyor and scanned with a high-speed laser system. In variousembodiments, particular lasers that make up the high-speed laser systemare configured to detect the presence of particular contaminates (e.g.,PVC or Aluminum). Flakes that are identified as not consistingessentially of PET may be blown from the main stream of flakes with airjets. In various embodiments, the resulting level of non-PET flakes isless than 25 ppm.

In various embodiments, the system is adapted to ensure that the PETpolymer being processed into filament is substantially free of water(e.g., entirely free of water). In a particular embodiment, the flakesare placed into a pre-conditioner for between about 20 and about 40minutes (e.g., about 30 minutes) during which the pre-conditioner blowsthe surface water off of the flakes. In particular embodiments,interstitial water remains within the flakes. In various embodiments,these “wet” flakes (e.g., flakes comprising interstitial water) may thenbe fed into an extruder (e.g., as described in Step 2 below), whichincludes a vacuum setup designed to remove—among other things—theinterstitial water that remains present in the flakes following thequick-drying process described above. In various embodiments, no step istaken to remove surface water from the flakes. In various embodiments,no step is taken to remove interstitial water from the flakes.

Step 2: Using an Extrusion System to Melt and Purify PET Flakes

In particular embodiments, an extruder is used to turn the wet flakesdescribed above into a molten recycled PET polymer and to perform anumber of purification processes to prepare the polymer to be turnedinto BCF for carpet. As noted above, in various embodiments, after Step1 is complete, the recycled PET polymer flakes are wet (e.g., surfacewater is substantially removed (e.g., fully removed) from the flakes,but interstitial water remains in the flakes). In particularembodiments, these wet flakes are fed into a Multiple Rotating Screw(“MRS”) extruder 400. In other embodiments, the wet flakes are fed intoany other suitable extruder (e.g., a twin screw extruder, a multiplescrew extruder, a planetary extruder, or any other suitable extrusionsystem). An exemplary MRS Extruder 400 is shown in FIGS. 2 and 3. Aparticular example of such an MRS extruder is described in U.S.Published Patent Application 2005/0047267, entitled “Extruder forProducing Molten Plastic Materials”, which was published on Mar. 3,2005, and which is hereby incorporated herein by reference.

As may be understood from this figure, in particular embodiments, theMRS extruder includes a first single-screw extruder section 410 forfeeding material into an MRS section 420 and a second single-screwextruder section 440 for transporting material away from the MRSsection.

In various embodiments, the wet flakes are fed directly into the MRSextruder 400 substantially immediately (e.g., immediately) following thewashing step described above (e.g., without drying the flakes orallowing the flakes to dry). In particular embodiments, a system thatfeeds the wet flakes directly into the MRS Extruder 400 substantiallyimmediately (e.g., immediately) following the washing step describedabove may consume about 20% less energy than a system that substantiallyfully pre-dries the flakes before extrusion (e.g., a system thatpre-dries the flakes by passing hot air over the wet flakes for aprolonged period of time). In various embodiments, a system that feedsthe wet flakes directly into the MRS Extruder 400 substantiallyimmediately (e.g., immediately) following the washing step describedabove avoids the need to wait a period of time (e.g., up to eight hours)generally required to fully dry the flakes remove all of the surface andinterstitial water from the flakes).

The prior art teaches that the PTT must be dried prior to extrusion andmanufacturing the fibers. It was unexpectedly found that themanufacturing process ran more efficiently when the PTT was not driedprior to the extrusion process.

FIG. 4 depicts a process flow that illustrates the various processesperformed by the MRS Extruder 400 in a particular embodiment. In theembodiment shown in this figure, the wet flakes are first fed throughthe MRS extruder's first single-screw extruder section 410, which may,for example, generate sufficient heat (e.g., via shearing) to at leastsubstantially melt (e.g., melt) the wet flakes.

The resultant polymer melt (e.g., comprising the melted flakes), invarious embodiments, is then fed into the extruder's MRS section 420, inwhich the extruder separates the melt flow into a plurality of differentstreams (e.g., 4, 6, 8, or more streams) through a plurality of openchambers. FIG. 3 shows a detailed cutaway view of an MRS Section 420according to a particular embodiment. In particular embodiments, such asthe embodiment shown in this figure, the MRS Section 420 separates themelt flow into eight different streams, which are subsequently fedthrough eight satellite screws 425A-H. As may be understood from FIG. 2,in particular embodiments, these satellite screws are substantiallyparallel (e.g., parallel) to one other and to a primary screw axis ofthe MRS Machine 400.

In the MRS section 420, in various embodiments, the satellite screws425A-H may, for example, rotate faster than (e.g., about four timesfaster than) in previous systems. As shown in FIG. 3, in particularembodiments: (1) the satellite screws 425A-H are arranged within asingle screw drum 428 that is mounted to rotate about its central axis;and (2) the satellite screws 425A-H are configured to rotate in adirection that is opposite to the direction in which the single screwdrum rotates 428. In various other embodiments, the satellite screws425A-H and the single screw drum 428 rotate in the same direction. Inparticular embodiments, the rotation of the satellite screws 425A-H isdriven by a ring gear. Also, in various embodiments, the single screwdrum 428 rotates about four times faster than each individual satellitescrew 425A-H. In certain embodiments, the satellite screws 425A-H rotateat substantially similar (e.g., the same) speeds.

In various embodiments, as may be understood from FIG. 4, the satellitescrews 425A-H are housed within respective extruder barrels, which may,for example be about 30% open to the outer chamber of the MRS section420. In particular embodiments, the rotation of the satellite screws425A-H and single screw drum 428 increases the surface exchange of thepolymer melt (e.g., exposes more surface area of the melted polymer tothe open chamber than in previous systems). In various embodiments, theMRS section 420 creates a melt surface area that is, for example,between about twenty and about thirty times greater than the meltsurface area created by a co-rotating, twin screw extruder. In aparticular embodiment, the MRS section 420 creates a melt surface areathat is, for example, about twenty five times greater than the meltsurface area created by a co-rotating twin screw extruder

In various embodiments, the MRS extruder's MRS Section 420 is fittedwith a Vacuum Pump 430 that is attached to a vacuum attachment portion422 of the MRS section 420 so that the Vacuum Pump 430 is incommunication with the interior of the MRS section via a suitableopening 424 in the MRS section's housing. In still other embodiments,the MRS Section 420 is fitted with a series of Vacuum Pumps. Inparticular embodiments, the Vacuum Pump 430 is configured to reduce thepressure within the interior of the MRS Section 420 to a pressure thatis between about 0.5 millibars and about 5 millibars. In particularembodiments, the Vacuum Pump 430 is configured to reduce the pressure inthe MRS Section 420 to less than about 1.5 millibars (e.g., about 1millibar or less). The low-pressure vacuum created by the Vacuum Pump430 in the MRS Section 420 may remove, for example: (1) volatileorganics present in the melted polymer as the melted polymer passesthrough the MRS Section 420; and/or (2) at least a portion of anyinterstitial water that was present in the wet flakes when the wetflakes entered the MRS Extruder 400. In various embodiments, thelow-pressure vacuum removes substantially all (e.g., all) of the waterand contaminants from the polymer stream.

In a particular example, the Vacuum Pump 430 comprises three mechanicallobe vacuum pumps (e.g., arranged in series) to reduce the pressure inthe chamber to a suitable level (e.g., to a pressure of about 1.0millibar). In other embodiments, rather than the three mechanical lobevacuum pump arrangement discussed above, the Vacuum Pump 430 includes ajet vacuum pump fit to the MRS extruder. In various embodiments, the jetvacuum pump is configured to achieve about 1 millibar of pressure in theinterior of the MRS section 420 and about the same results describedabove regarding a resulting intrinsic viscosity of the polymer melt. Invarious embodiments, using a jet vacuum pump can be advantageous becausejet vacuum pumps are steam powered and therefore substantiallyself-cleaning (e.g., self-cleaning), thereby reducing the maintenancerequired in comparison to mechanical lobe pumps (which may, for example,require repeated cleaning due to volatiles coming off and condensing onthe lobes of the pump). In a particular embodiment, the Vacuum Pump 430is a jet vacuum pump is made by Arpuma GmbH of Bergheim, Germany.

In particular embodiments, after the molten polymer is run the throughthe multi-stream MRS Section 420, the streams of molten polymer arerecombined and flow into the MRS extruder's second single screw section440. In various embodiments, the single stream of molten polymer is nextrun through a filtration system 450 that includes at least one filter.In a particular embodiment, the filtration system 450 includes twolevels of filtration (e.g., a 40 micron screen filter followed by a 25micron screen filter). Although, in various embodiments, water andvolatile organic impurities are removed during the vacuum process asdiscussed above, particulate contaminates such as, for example, aluminumparticles, sand, dirt, and other contaminants may remain in the polymermelt. Thus, this filtration step may be advantageous in removingparticulate contaminates (e.g., particulate contaminates that were notremoved in the MRS Section 420).

In particular embodiments, a viscosity sensor 460 (see FIG. 4) is usedto sense the melt viscosity of the molten polymer stream following itspassage through the filtration system 450. In various embodiments, theviscosity sensor 460, measures the melt viscosity of the stream, forexample, by measuring the stream's pressure drop across a known area. Inparticular embodiments, in response to measuring an intrinsic viscosityof the stream that is below a predetermined level (e.g., below about 0.8g/dL), the system may; (1) discard the portion of the stream with lowintrinsic viscosity; and/or (2) lower the pressure in the MRS Section420 in order to achieve a higher intrinsic viscosity in the polymermelt. In particular embodiments, decreasing the pressure in the MRSSection 420 is executed in a substantially automated manner (e.g.,automatically) using the viscosity sensor in a computer-controlledfeedback control loop with the vacuum section 430.

In particular embodiments, removing the water and contaminates from thepolymer improves the intrinsic viscosity of the recycled PET polymer byallowing polymer chains in the polymer to reconnect and extend the chainlength. In particular embodiments, following its passage through the MRSSection 420 with its attached Vacuum Pump 430, the recycled polymer melthas an intrinsic viscosity of at least about 0.60 dL/g (e.g., of betweenabout 0.60 dL/g and about 1.00 dL/g, or between about 0.75 dL/g andabout 1.00 dL/g). In particular embodiments, passage through the lowpressure MRS Section 420 purifies the recycled polymer melt (e.g., byremoving the contaminants and interstitial water) and makes the recycledpolymer substantially structurally similar to (e.g., structurally thesame as) pure virgin PET polymer. In particular embodiments, the waterremoved by the vacuum includes both water from the wash water used toclean the recycled PET bottles as described above, as well as fromunreacted water generated by the melting of the PET polymer in thesingle screw heater 410 (e.g., interstitial water). In particularembodiments, the majority of water present in the polymer is wash water,but some percentage may be unreacted water.

Step 3: Mixing Polymer Fed into Spinning Machine to be Turned intoCarpet Yarn

In particular embodiments, after the recycled PET polymer has beenextruded and purified by the above-described extrusion process, themolten polymer is cooled into pellets and mixed with PTT and PEN. Thismixture is then melted and fed into a BCF (or “spinning”) machine 500that is configured to turn the molten polymer into bulked continuousfilament.

Step 4: Mixed Polymer Fed into Spinning Machine to be Turned into CarpetYarn

In particular embodiments, the spinning machine 500 extrudes moltenpolymer through small holes in a spinneret in order to produce carpetyarn filament from the polymer. In particular embodiments, the moltenpolymer blend cools after leaving the spinneret. The carpet yarn is thentaken up by rollers and ultimately turned into filaments that are usedto produce carpet. In various embodiments, the carpet yarn produced bythe spinning machine 500 may have a tenacity between about 2 gram-forceper unit denier (gf/den) and about 9 gf/den. In particular embodiments,the resulting carpet yarn has a tenacity of at least about 2 gf/den.

In particular embodiments, the spinning machine 500 used in the processdescribed above is the Sytec One spinning machine manufactured byOerlika Neumag of Neumuenster, Germany. The Sytec One machine may beespecially adapted for hard-to-run fibers, such as nylon orsolution-dyed fibers, where the filaments are prone to breakage duringprocessing. In various embodiments, the Sytec One machine keeps the runsdownstream of the spinneret as straight as possible, uses only onethreadline, and is designed to be quick to rethread when there arefilament breaks.

Although the example described above describes using the Sytec Onespinning machine to produce carpet yarn filament from the polymer, itshould be understood that any other suitable spinning machine may beused. Such spinning machines may include, for example, any suitableone-threadline or three-threadline spinning machine made by OerlikaNeumag of Neumuenster, Germany or any other company.

In various embodiments, the improved strength of the recycled PETpolymer generated using the process above allows the polymer blend to berun at higher speeds through the spinning machine 500 than would bepossible using pure virgin PET polymer. This may allow for higherprocessing speeds than are possible when using virgin PET polymer.

Alternate Embodiments

Non-MRS Extrusion System

In particular embodiments, the process may utilize a polymer flowextrusion system other than the MRS extruder described above. Thealternative extrusion system may include for example, a twin screwextruder, a multiple screw extruder, a planetary extruder, or any othersuitable extrusion system. In a particular embodiment, the process mayinclude a plurality of any combination of any suitable conical screwextruders (e.g., four twin screw extruders, three multiple screwextruders, etc.).

Variations on Mixing Polymers

The above-described method describes an indirect method of preparing thePET/PTT/PEN blend, in which PET flakes are converted into PET pellets,the PET pellets are mixed with PEN pellets and PTT pellets, and the mixof pellets if fed into a subsequent extruder. Alternate embodiments ofmixing the polymers include:

1. PET flakes, PEN pellets, and PTT pellets are mixed and fed into theMRS extruder.

2. PET flakes, PEN pellets, and PTT pellets are compounded into a singlepellet, which is fed into a subsequent extruder. In this embodiment, theMRS system offers the advantage of minimizing IV loss during theproduction of the compounded pellets.

In some alternate embodiments, there is no step of cooling the PET intopellets and subsequently combining them with the PTT and PEN. In thisalternate embodiment, the melted terpolymer can be fed directly into asuitable spinning machine to be turned into fiber.

Non-Recycled PET

The above-described embodiment describes the use of recycled PET (rPET)in preparing the terpolymer fiber. In an alternate embodiment, the fiberis prepared using virgin PET. In such an embodiment, some or all of thesub-parts of Step 1 are not performed.

Example 1 —PET and PET Blends Dyeability

A number of PET and PET blend fibers were tested for dyeability. Thefibers were produced via a Multiple Rotating Screw (MRS) extruder, viathe direct method in which the polymers were combined in dry form priorto melting and purification in the MRS extruder, as describedhereinabove. The components of the different tested fibers aresummarized below in Table 1.

TABLE 1 Summary of Fiber Compositions Components Fiber (remainder isPET) Notes 1 Light yarn in a barber pole 2 Dark yarn in a barber pole 310% PTT 4 10% PTT, 1% PEG 5 14% PTT 6 20% PTT SideStream 7 122 filaments(versus 150 filaments in Fiber 1) A 10% PEN B 15% PEN C 10% PEN, 6.5%PTT D 15% PEN, 6.5% PTT E 10% PEN, 10% PTT F 15% PEN, 10% PTT

Fibers 1-7 were PET or PET/PTT blends. Fibers A-F were PET/PEN orPET/PEN/PTT blends.

These fibers were knitted into sleeves. Each sleeve comprisedalternating portions of Fiber 1 and each of the other fibers. FIG. 5shows the sleeves for each of fibers A-F and 7, post-dyeing. Fibers 2-6were tested, but are not represented in FIG. 5. The bottom-most portionof each sleeve is Fiber 1. Table 2 shows which sleeves correspond towhich fiber. Each fiber corresponds to two sleeves, one of which wasdyed as-spun, and the other of which was dyed post heat-setting.

TABLE 2 Sleeves of Fibers A-F and 7 Fiber Sleeves A 22 (as-spun), 23(heat-set) B 24 (as-spun), 25 (heat-set) C 26 (as-spun), 27 (heat-set) D28 (as-spun), 29 (heat-set) E 30 (as-spun), 31 (heat-set) F 32(as-spun), 33 (heat-set) 7 34 (as-spun), 35 (heat-set)

Each sleeve was dyed in a laundrometer. Color measurements were recordedby spectrophotometer. The color strength of each fiber relative to thecolor strength of Fiber 1 in its own sleeve (Str %) was recorded. Table3 summarizes the Str % for each of the different fibers, as-spun (Str %As-sp) and following heat setting (Str % HS). A higher Str % indicatesgreater dyeability.

TABLE 3 Average dyeability for each fiber blend Fiber Str % As-sp Str %HS 1 100 100 2 263 430 3 174 187 4 224 267 5 224 307 6 217 270 7 89 95 A114 124 B 125 129 C 228 260 D 236 253 E 308 347 F 358 384

Example 2: Physical Property Testing

Some of the fibers were also tested for their total recovery (% TR),crimp (% CO), shrinkage (% FS), elongation (%), and tenacity (g/denier).Tensile properties were tested on a Textechno Statimat ME+ tensiletester. Bulk, crimp, shrinkage, and recovery were tested on aLawson-Hemphill TYT machine. Those results are summarized in Table 4.

TABLE 4 Physical property data for certain fiber blends ElongationTenacity Fiber % TR % CO % FS (%) (g/denier) 1 15.0 11 4.5 33 3.1 314.42 9.91 5 40.2 2.6 4 14.45 9.69 5.28 39.5 2.49 5 14.45 8.98 6.01 41.42.35 A 15.63 11.3 4.88 31.15 2.98 B 15.63 10.62 5.59 31.94 2.6 C 14.4710.45 4.49 35.12 2.55 D 14.3 9.86 4.91 37.03 2.39 E 13.71 9.73 4.4139.93 2.42 F 14.25 8.83 5.94 37.15 2.05

The combined data show the benefits of the presence of PEN in PET/PTTblends. The presence of PEN, unexpectedly, causes the effect ondyeability of additional PTT to be increased.

To demonstrate, the Str % of as-spun Fiber 1 (0% PTT) is 100%. Adding10% PTT (as in Fiber 3) gives a Str % of 174% (a 74% relative increase).Adding another 10% PTT (to have 20% PTT, as in Fiber 6) gives a Str % of224% (only a relative increase of 29% compared to Fiber 3).

The difference in dyeability that 10% of PTT makes is much greater inPET blends when PEN is present. Comparing as-spun Fiber A (10% PEN) toas-spun Fiber E (10% PEN and 10% PTT), an increase in Str % from 114% to308% is seen (a relative increase of 170%). A similar result is seenwhen comparing as-spun Fiber B (15% PEN) to as-spun Fiber F (15% PEN and10% PTT), as an increase from 125 to 328 Str % occurs (a relativeincrease of 162%).

PET/PTT/PEN blends also demonstrate a favorable tradeoff between theincrease in dyeability and the decreased strength caused by the additionof PTT. This can be seen when comparing the dyeability and physicalproperty data of, among other pairings, Fibers C and E. Theircompositions, physical property and dyeability data are reproduced inTable 5:

TABLE 5 Physical property and dyeability data for Fibers C and E Str % %% Elongation Tenacity % Fiber PEN PTT TR CO FS (%) (g/denier) As-sp C10% 6.5% 14.47 10.45 4.49 35.12 2.55 228 E 10%  10% 13.71 9.73 4.4139.93 2.42 308

Adding 4.5% PTT (going from Fiber C to Fiber E) has relatively minornegative effects on the physical properties. The average reduction inthe five properties is 6.5%, including a reduction in tensile strength(tenacity) of 5.1%. The improvement in dyeability for the same change,however, is a relative increase of 35%. Meanwhile, going from 100% PETto a 90% PET/10% PTT blend (i.e. from Fiber 1 to Fiber 3) showsapproximately a 16% decrease in tensile strength. Prior research onPET/PTT blends shows as high as a 30% decrease in tensile strength whengoing from 100% PET to a 90% PET/10% PTT blend (Supahol et al.).

Further, independently adding 10% of PTT or PEN yields dye uptakeincreases of 87% and 24% respectively while the combination yields anunexpected 247% increase. Notably, the tenacity of the combination fiberwas still suitable, whereas combining either PTT or PEN in quantitieshigh enough to achieve a similar dye increase results in fibers that areunsuitable.

CONCLUSION

Many modifications and other embodiments of the inventions set forthherein will come to mind to one skilled in the art to which theseinventions pertain having the benefit of the teachings presented in theforegoing descriptions. Therefore, it is to be understood that theinventions are not to be limited to the specific embodiments disclosedand that modifications and other embodiments are intended to be includedwithin the scope of this disclosure. Although specific terms areemployed herein, they are used in a generic and descriptive sense onlyand not for purposes of limitation.

LIST OF REFERENCES CITED

-   Supahol et al., “Thermal, Crystallization, Mechanical, and    Rheological Characteristics of Poly(trimethylene    terephthalate)/Poly(ethylene terephthalate) Blends”, Journal of    Polymer Science: Part B: Polymer Physics, 42:676-686 (2004)

What is claimed is:
 1. A fiber comprising a polymer blend, said polymerblend comprising: a) about 1% by weight—about 15% by weightpolytrimethylene terephthalate polymer; and b) about 1% by weight—about15% by weight polyethylene naphthalate polymer; wherein the remainder ofsaid polymer blend is polyethylene terephthalate polymer; wherein thefiber is a bulked continuous filament (BCF).
 2. The fiber of claim 1,comprising about 5% by weight to about 15% by weight polytrimethyleneterephthalate polymer.
 3. The fiber of claim 1, comprising about 5% byweight to about 15% by weight polyethylene naphthalate polymer.
 4. Thefiber of claim 1, comprising about 8% by weight polytrimethyleneterephthalate polymer and about 10% by weight polyethylene naphthalatepolymer.
 5. The fiber of claim 1, wherein the fiber is as-spun, or isheat-set.
 6. The fiber of claim 1, wherein the fiber exhibits increaseddyeability compared to a similar fiber where a portion of or all of thepolytrimethylene terephthalate polymer or polyethylene naphthalatepolymer is replaced by polyethylene terephthalate polymer; and whereinthe increase in dyeability is at least about 1%.
 7. The fiber of claim1, wherein the fiber exhibits an improvement in a physicalcharacteristic selected from the group consisting of total recovery,elongation, crimp, tenacity, and shrinkage, compared to a similar fiberwhere a portion of the polyethylene naphthalate polymer is replaced bypolyethylene terephthalate polymer; and wherein the improvement is atleast 1%.
 8. The fiber of claim 1, wherein one, two, or all three of thepolyethylene terephthalate polymer, the polytrimethylene terephthalatepolymer, and the polyethylene naphthalate polymer are recycled.
 9. Thefiber of claim 1, further comprising a component selected from the groupconsisting of finishing agents, delusterants, viscosity boosters,optical brighteners, matting agents, thermal stabilizing agents,anti-oxidative agents, anti-static agents, pigments, ultra-violetblocking agents, and combinations thereof.
 10. A yarn or a carpetcomprising a fiber according to claim
 1. 11. A method of manufacturingbulked continuous carpet filament, said method comprising: (A) providinga multi-screw extruder that comprises: (i) a first satellite screwextruder, said first satellite screw extruder comprising a firstsatellite screw that is mounted to rotate about a central axis of saidfirst satellite screw; (ii) a second satellite screw extruder, saidsecond satellite screw extruder comprising a second satellite screw thatis mounted to rotate about a central axis of said second satellitescrew; and (iii) a pressure regulation system that is adapted tomaintain a pressure within said first and second satellite screwextruders between about 0 millibars and about 1.8 millibars; (B) usingsaid pressure regulation system to reduce a pressure within said firstand second satellite screw extruders to between about 0 millibars andabout 1.8 millibars; (C) while maintaining said pressure within saidfirst and second satellite screw extruders between about 0 millibars andabout 1.8 millibars, passing a melt comprising a polymer through saidmulti-screw extruder so that: (1) a first portion of said melt passesthrough said first satellite screw extruder, and (2) a second portion ofsaid melt passes through said second satellite screw extruder; and (D)after said step of passing said melt of polymer through said multi-screwextruder, forming said polymer into a bulked continuous carpet filament;wherein said bulked continuous carpet filament comprises a polymer blendcomprising a) about 1% by weight—about 15% by weight polytrimethyleneterephthalate polymer (PTT); and b) about 1% by weight—about 15% byweight polyethylene naphthalate polymer (PEN); wherein the remainder ofsaid polymer blend is polyethylene terephthalate polymer (PEN); andwherein the PTT is or is not dried prior to step (C).
 12. The method ofclaim 11, wherein said polymer is a polyethylene terephthalate polymer,and further comprising after step (C) and before step (D), cooling saidmelt of polymer so as to form pellets, and mixing said pellets withpolytrimethylene terephthalate polymer pellets, and polyethylenenaphthalate polymer pellets.
 13. The method of claim 11, wherein saidmulti-screw extruder is a first extruder; and said method furthercomprises: i) passing a plurality of flakes of PET through a secondextruder; and ii) while passing said plurality of flakes through saidsecond extruder, using said second extruder to heat said plurality offlakes to a temperature that is sufficient to at least substantiallymelt said plurality of flakes to form said polymer melt.
 14. The methodof claim 13, wherein said PET flakes are recycled PET flakes, andwherein said method further comprises, before said step of passing saidplurality of flakes through said second extruder: washing said pluralityof PET flakes; scanning said washed plurality of PET flakes to identifyany of said plurality of flakes that comprise material other than PET;and removing at least one of said identified flakes that comprisematerial other than PET.
 15. The method of claim 11, wherein the melt instep (C) is a melt comprising polyethylene terephthalate, polyethylenenaphthalate, and polytrimethylene terephthalate.
 16. The method of claim15, wherein a mixture of PET flakes, PEN pellets, and PTT pellets is fedinto the multi-screw extruder, or a compounded pellet comprising PET,PEN, and PTT is fed into the multi-screw extruder.
 17. A method ofmanufacturing a fiber comprising a polymer blend of PET, PEN, and PTT,comprising: a) providing a plurality of pellets, each pellet comprisingPET, PEN, and PTT; and b) melting said plurality of pellets with anextruder so as to form a melt; and c) processing said melt with aspinning machine, so as to form said fiber; wherein said fiber is abulked continuous filament (BCF); and wherein said fiber comprises apolymer blend, said polymer blend comprising: c) about 1% byweight—about 15% by weight polytrimethylene terephthalate polymer; andd) about 1% by weight—about 15% by weight polyethylene naphthalatepolymer; wherein the remainder of said polymer blend is polyethyleneterephthalate polymer.
 18. The method of claim 11, wherein said polymerblend comprises about 5% by weight to about 15% by weightpolytrimethylene terephthalate polymer, or wherein said polymer blendcomprises about 5% by weight to about 15% by weight polyethylenenaphthalate polymer.
 19. A yarn comprising the fiber of claim
 1. 20. Acarpet comprising the fiber of claim 1.